Roy, examination committee chair associate professor of mechanical engineering university of nevada, las vegas the susceptibility of alloy ep823 to stress corrosion cracking has been evaluated. Resistance to stresscorrosion cracking is the most obvious advantage of the ferritic stainless steels. Generally, the term martensitic refers to a hard crystalline structure. Repair welding of cracked steam turbine blades using austenitic and martensitic stainlesssteel consumables article in nuclear engineering and design 20623. The blades must be tough and resistant to stress, cracking and corrosion.
Transgranular stress corrosion cracking of 304l stainless steel pipe clamps in direct use geothermal water heating applications michael f. Transgranular stress corrosion cracking of 304l stainless. Study on stress corrosion cracking sensitivity of crnimov steam turbine rotor steels. Valbruna produces several types of stainless steels, nickel and titanium alloys for turbine hardware as well as turbine blading and vanes. Heat treatment of welded %cr4%ni martensitic stainless. Sensitivity to sulfide scc increases at higher material hardness levels, and the nace mr0175 1993 revision standard. Stainless steels types 304 and 316 can be considered resistant below 80 degc, up to the limit of solubility. Welding is considered the most complicated fabrication process for the super 12% cr steels because of their high hardenability. In this paper, the stress corrosion behavior of 12crnimovn martensite stainless steels used for steam turbine lp last stage blade in 3vol% nacl solution was studied, the constant stress is about 95%, 85%, 65% and 35% of yield stress respectively and the test was lasted for 3000 hours, the stress corrosion behavior was studied and then, the.
Degradation of the mechanical integrity of steam turbine steels due. Laboratory samples of 12 wt% cr martensitic stainless steels, used for lowpressure steam turbine blades, previously exposed to condensing. The blades drive the turbine which generates electricity. Martensitic stainless steels are widely used as steam turbine blades 16.
Stress corrosion cracking initiates at small corrosion pits or crevice corrosion and scc susceptibility increases with increasing hardness of the steel. It is important to realize that not all corrosive environments promote the formation of stress corrosion cracks. Swiss army knives are made of martensitic stainless steel. This work presents the results of a comprehensive study concerning stress corrosion crack growth rates in steam turbine rotor steels exposed to hot water. Martensitic stainless steels stainless foundry steel castings. Stress corrosion cracking sensitivity of super martensitic. Schematic of the turbine blade with the fractured region as shown. Characteristics of corrosion fatigue failed steam turbine blades are summarized as follows 2. Accordingly, the development of effective localized corrosion inhibitors is essential for the successful avoid.
The effects of stress intensity, temperature, and dissolved gases in the water have been investigated. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic. This paper is focused on the influence of stress states on deformationinduced a martensitic transformation in aisi type 316 austenitic stainless steel in the form of round bars and metallic sheets. Starting from the high alloyed martensitic steels down to precipitation hardening stainless steels, hardness and abrasion resistance decrease while. Studies of stress corrosion in x12cr and x20cr steels used for rotor blades of steam turbines have been conducted for determining the average rate of corrosion cracking development da dt. In this work, we had studied two kinds of commercial jethete m152 steels, and both steels have the similar compositions and the same heat treatment process. Caustic stress corrosion cracking inspectioneering. The effect of material properties steel cleanliness, yield strength. Corrosion and microstructural characterization of martensitic. Stress corrosion cracking of steel in liquefied ammonia. Erosionfatigue of steam turbine blades request pdf. Stress corrosion cracking of crni martensitic stainless steels for steam turbine blades.
The predictive methodology to be developed will include pit growth in. In this work, we had studied two kinds of commercial jethete m152 steels, and both steels have the similar. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Martensitic stainless steels corrosion fatigue failure of steam turbine blades has been a big concern in the world for more than 30 years. Effect of steam on high temperature oxidation behaviour of aluminaforming alloys pint et al.
Corrosion fatigue crack initiation behavior of stainless. Stresscorrosion cracking, materials performance and. Resistance to stress corrosion cracking is the most obvious advantage of the ferritic stainless steels. Finite element calculations and material tests were done to find the root cause of rotor cracking. Stress corrosion of nibased superalloys brooking et al. Stress corrosion cracking resistance of martensitic.
Martensitic stainless steels are normally hardened by heating in the austenitizing range of 925 to 1065. Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially stress corrosion cracking of austenitic stainless steel. For turbine blade materials, the high temperature and high pressure steam working condition often result in stress corrosion cracking. The typical operating temperature of the steam is around 600 c.
The choice of stainless grades then becomes quite limited. Although moderately high strength steels have, in general, performed admirably in the long time service expected of turbine components, there have been a number of instances of stress corrosion cracking in these components. Stress corrosion cracking of a 60mw steam turbine rotor request. Application and characteristics of lowcarbon martensitic.
These past few years, a limited number of cases of intergranular stress corrosion cracking igscc have been detected in cold worked areas of non sensitized. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Corrosion inhibition of stress corrosion cracking and. In this project the oxidation resistance of two candidate austenitic stainless steels i. Stress corrosion cracking of crni martensitic stainless steels for.
Deformation induced martensite in aisi 316 stainless steel. Verona, c and higginson, r 2009 stress corrosion cracking of crni martensitic stainless steels for steam turbine blades, european corrosion congress 2009. Banaszkiewicz 2 1 thermochemical power department, iffm polish academy of sciences, gdansk 2alstom power sp. Corrosion fatigue crack propagation rates for steam turbine. Stress corrosion cracking and corrosion fatigue of steam turbine rotor and blade materials research on high temperature materials which are critical for the safe and efficient operation of power engineering equipment has been an important feature of cost concerted action programmes for the last eighteen years. Ferritic steels resist chloride and caustic stress corrosion cracking very well. Sep 06, 2019 industrially, martensitic steel is one of the three types of stainless steel alloy which is also a corrosion resistant alloy. Stress corrosion cracking and corrosion fatigue of steam.
More recent examples include stress corrosion of steam turbine blading and rotors, nuclear piping, aircraft structures. Cr and 4% ni is used for most pelton, kaplan and francis turbines in hydroelectric power plants. Stress corrosion cracking of a 60 mw steam turbine rotor. Stress corrosion cracking behavior of martensitic stainless steels is evaluated as a function of tempering temperature by means of three points bending scc tests in high purity water at 70288c. Cyclic fatigue characteristics of 10%cr blade steels for advanced steam turbine jinik suk, kukcheol kim, byunghoon kim and jeongtae kim doosan heavy industries and construction co. Repair welding of cracked steam turbine blades using. The working temperature of steam turbine was around 600 700 c. The accumulation of damage due to localized corrosion pitting, stress corrosion cracking scc and corrosion fatigue cf in low pressure steam turbines components, such as blades, discs and rotors, has been consistently identified as being among the main causes of turbine failures 1, 2. Roy, examination committee chair associate professor of mechanical engineering university of nevada, las vegas this investigation is focused on the evaluation of stress corrosion cracking scc. Pits geometry analysis and strength tests have been conducted. This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Corrosion resistance of ferritic stainless steels total. Although moderately high strength steels have, in general, performed admirably in the long time service expected of turbine components, there have been a number of instances of stress corrosion cracking in. Effect of pitting corrosion on strength of aisi 410.
The problem of stress corrosion cracking is still of paramount importance both in conventional and nuclear steam turbines and also affects the steam turbine blades, although for blades corrosion fatigue is a more important issue. Stress corrosion cracking of crni martensitic stainless. Stress corrosion cracking is a mechanicalenvironmental failure. Stress corrosion cracking behavior of martensitic stainless. The specificity of environments that will promote stress corrosion cracking is significant. General corrosion resistance in steam is better than the grades containing less than 12% chromium. Stress corrosion cracking of low pressure steam turbine blade and rotor materials stress corrosion cracking of a 14 wt% cr martensitic stainless steel, with commercial names ph15cr5ni, fv520b or x4crnicumo155, used for the manufacture of low pressure turbine blades, has been studied with the intention of gaining a better understanding of the processes involved, how they occur and why. This health and safety executive sector information minute sim 5200218 outlines the background to stress corrosion cracking failure hazards to stainless steel items used in indoor swimming poll buildings. Corrosion fatigue crack initiation behavior of stainless steels 2. In the present paper, effects of pitting corrosion on the strength of members made of aisi 410 martensitic stainless steel were investigated. Selection of stainless steels for handling sodium hydroxide naoh sodium hydroxide caustic soda is a strong base, used widely for cleaning metals. These results are interpreted as a further qualitative evidence of an evolution of the microstructure leading to the formation of new precipitates.
The supermartensitic stainless steels used in these blades are perfect for use in this application. Stress corrosion behavior of 12cr martensite steel for steam. Turbine blades valbruna produces several types of stainless steels, nickel and titanium alloys for turbine hardware as well as turbine blading and vanes. A brand new cvdcoated grade, especially developed and optimized for turbineblade milling has enabled performance to be improved for the wide range of martensitic stainless steel blades. Of the remaining precipitation hardening stainless steels tested, a286, almar 362, and unitemp 212 were highly resistant to stress corrosion cracking in all test tempers or conditions. Stress corrosion modeling in steam turbine blades kucharski 1, j. Stress corrosion cracking on coldworked austenitic stainless steels in pwr environment abstract types 304l and 316l austenitic stainless steels ss are widely used in pwr environment.
Stress corrosion cracking of low pressure steam turbine. Specimens were exposed to the salt mist environment of 1,2 ppm nacl concentration in temperature of 60 c. Materials we are specialized in the forging and manufacturing of turbine blades and aerospace components in a wide range of materials, including stainless steel, titanium and nickel alloys. A higher percentage of carbon makes martensitic steel tougher and harder. Stress corrosion cracking resistance of martensitic stainless steels for transmutation applications by phani p. Effect of pitting corrosion on strength of aisi 410 stainless.
Martensitic stainless steels stainless foundry steel. Abstractstress corrosion cracking data for steam turbine disc steels. Generally, three groups of factors influence the phenomenon of stress corrosion cracking. They also have good weldability due to the low c concentration, therefore, the super cr for flow line has also been developed and applied as weldable cr steels 58. Stress corrosion cracking resistance of martensitic stainless. Stress corrosion cracking scc is a sudden cracking and failure of a. Pits geometry analysis established the maximum pit. Stress corrosion cracking of stainless steel components in. Commission of the european communities cost stress corrosion cracking and corrosion fatigue of steamturbine rotor and blade materials m. Repair welding of cracked steam turbine blades using austenitic and martensitic stainless steel consumables article in nuclear engineering and design 20623. Analysis of inside diameter stress corrosion cracking scc of stainless steels in pwrs has shown that aggravating circumstances for scc initiation and growth generally include offnormal water chemistry in regions where the.
Stress corrosion cracking and hydrogen embrittlement of martensitic alloy ep823 by mohammad kamal hossain dr. Corrosion fatigue crack propagation rates for steam. Blades are typically manufactured from 12cr martensitic stainless steel such as. Clean steels for steam turbine rotorstheir stress corrosion. The fecr3mo3ni stainless steels are modified into martensitic stainless steels for steam turbine blades application. Stress corrosion cracking was the root cause of blade grooves failure. Publications for rebecca higginson loughborough university. Chapter 4, stresscorrosion cracking of stainless steels, was revised by john. Stresscorrosion cracking materials performance and evaluation second edition edited by russell h. Grade ca6nm, especially for heavy section water turbine components, and replacing the older 12% cr cast steels to ca15 and similar specifications. In this investigation, the effect of the welding conditions on. Stress corrosion cracking and hydrogen embrittlement of. Abstract it has been reported that the super martensitic stainless steel welded joints may be susceptible to stress corrosion cracking scc in co2 environment at elevated temperatures.
A high hardness, corrosion and fatigue resistance martensitic. Vulnerability to scc was eliminated by reducing the proof stress and local notch stresses of the weld repaired grooves. Laboratory samples of 12 wt% cr martensitic stainless steels, used for lowpressure steam turbine blades, previously exposed to condensing steam at 95c for various times, have been examined using optical and scanning electron microscopy sem, energy dispersive xray spectroscopy eds and electron backscatter diffraction ebsd. Scc and crevice corrosion inhibition of steam turbine astm. C and 600 c to investigate the cyclic behaviour of a fv566 martensitic turbine steel. Industrially, martensitic steel is one of the three types of stainless steel alloy which is also a corrosionresistant alloy. Nickel and copper residuals lower resistance of these steels to stress corosion. Stress corrosion cracking of stainless steels in swimming pool buildings. Effective and widespread application of any alloy is dependent upon good weldability and this factor alone has previously restricted the exploitation of ferritic and martensitic stainless steels more than any. Overview steam turbines part 2 stress corrosion cracking of. These grades offer better erosion or wear resistance because of the high hardness values that can be obtained through heat treatment.
Stress corrosion cracking of highstrength steels uq espace. This alloy can have a low or high percentage of carbon, which gives it the properties of toughness and hardness. Lowpressure steam turbines are susceptible to stresscorrosion cracking scc. The material is supplied in the form of billets round cornered squares and rounds for forging, heat treated flat bars and rounds for machining. The material is supplied in the form of billets round cornered squares and rounds for forging. The corrosion performance of the weldable cr steels including girth welding has been focused and discussed mainly based on the sulfide stress cracking ssc in a slightly. Stress corrosion behavior of 12cr martensite steel for. Special attention has been given to the influence of impurities and alloying elements in the steel such.
Abstract the paper discusses stress corrosion cracking scc of stainless steel components due to the ingress of caustic into steam systems. Starting from the high alloyed martensitic steels down to precipitation hardening stainless steels, hardness and abrasion resistance decrease while corrosion resistance increases. There can be a risk of stress corrosion cracking scc attack at higher temperatures. Laboratory samples of 12 wt% cr martensitic stainless steels, used for low pressure steam turbine blades, previously exposed to condensing. Stainless steel compressor blades in power generation industries commonly suffer from pitting corrosion.
232 1312 1513 708 200 816 1155 563 927 412 1422 749 1163 203 88 961 1411 645 1486 482 986 333 1086 756 227 1393 458 80 640 506 177 713 1291 219 747 330 1357 34